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Analyzing the energy intensity and greenhouse gas emission of Canadian oil sands crude upgrading through

Anton ALVAREZ-MAJMUTOV,Jinwen CHEN

《化学科学与工程前沿（英文）》 2014年第8卷第2期页码 212-218 doi: 10.1007/s11705-014-1424-z

摘要： This paper presents an evaluation of the energy intensity and related greenhouse gas/CO emissions of integrated oil sands crude upgrading processes. Two major oil sands crude upgrading schemes currently used in Canadian oil sands operations were investigated: coking-based and hydroconversion-based. The analysis, which was based on a robust process model of the entire process, was constructed in Aspen HYSYS and calibrated with representative data. Simulations were conducted for the two upgrading schemes in order to generate a detailed inventory of the required energy and utility inputs: process fuel, steam, hydrogen and power. It was concluded that while hydroconversion-based scheme yields considerably higher amount of synthetic crude oil (SCO) than the coker-based scheme (94 wt-% vs. 76 wt-%), it consumes more energy and is therefore more CO -intensive (413.2 kg CO /m vs. 216.4 kg CO /m ). This substantial difference results from the large amount of hydrogen consumed in the ebullated-bed hydroconverter in the hydroconversion-based scheme, as hydrogen production through conventional methane steam reforming is highly energy-intensive and therefore the major source of CO emission. Further simulations indicated that optimization of hydroconverter operating variables had only a minor effect on the overall CO emission due to the complex trade-off effect between energy inputs.

关键词： Oil sands crude upgrading hydroconversion process modeling greenhouse gas emissions

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Microbial community and functional genes in the rhizosphere of alfalfa in crude oil-contaminated soil

Yi ZHONG, Jian WANG, Yizhi SONG, Yuting LIANG, Guanghe LI

《环境科学与工程前沿（英文）》 2012年第6卷第6期页码 797-805 doi: 10.1007/s11783-012-0405-z

摘要： A rhizobox system constructed with crude oil-contaminated soil was vegetated with alfalfa ( L.) to evaluate the rhizosphere effects on the soil microbial population and functional structure, and to explore the potential mechanisms by which plants enhance the removal of crude oil in soil. During the 80-day experiment, 31.6% of oil was removed from the adjacent rhizosphere (AR); this value was 27% and 53% higher than the percentage of oil removed from the far rhizosphere (FR) and from the non-rhizosphere (NR), respectively. The populations of heterotrophic bacteria and hydrocarbon-degrading bacteria were higher in the AR and FR than in the NR. However, the removal rate of crude oil was positively correlated with the proportion of hydrocarbon-degrading bacteria in the rhizosphere. In total, 796, 731, and 379 functional genes were detected by microarray in the AR, FR, and NR, respectively. Higher proportions of functional genes related to carbon degradation and organic remediation, were found in rhizosphere soil compared with NR soil, suggesting that the rhizosphere selectively increased the abundance of these specific functional genes. The increase in water-holding capacity and decrease in pH as well as salinity of the soil all followed the order of AR>FR>NR. Canonical component analysis showed that salinity was the most important environmental factor influencing the microbial functional structure in the rhizosphere and that salinity was negatively correlated with the abundance of carbon and organic degradation genes.

关键词： crude oil-contaminated soil phytoremediation rhizosphere effects rhizobox functional genes

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Production of renewable fuels by blending bio-oil with alcohols and upgrading under supercritical conditions

Sainab Omar, Suzanne Alsamaq, Yang Yang, Jiawei Wang

《化学科学与工程前沿（英文）》 2019年第13卷第4期页码 702-717 doi: 10.1007/s11705-019-1861-9

摘要： The work studied a non-catalytic upgrading of fast pyrolysis bio-oil by blending under supercritical conditions using methanol, ethanol and isopropanol as solvent and hydrogen donor. Characterisation of the bio-oil and the upgraded bio-oils was carried out including moisture content, elemental content, pH, heating value, gas chromatography-mass spectrometry (GCMS), Fourier transform infrared radiation, C nuclear magnetic resonance spectroscopy, and thermogravimetric analysis to evaluate the effects of blending and supercritical reactions. The GCMS analysis indicated that the supercritical methanol reaction removed the acids in the bio-oil consequently the pH increased from 2.39 in the crude bio-oil to 4.04 after the supercritical methanol reaction. The ester contents increased by 87.49% after the supercritical methanol reaction indicating ester formation could be the major deacidification mechanism for reducing the acidity of the bio-oil and improving its pH value. Simply blending crude bio-oil with isopropanol was effective in increasing the C and H content, reducing the O content and increasing the heating value to 27.55 from 17.51 MJ·kg in the crude bio-oil. After the supercritical isopropanol reaction, the heating value of the liquid product slightly further increased to 28.85 MJ·kg .

关键词： bio-oil blending supercritical upgrading characterisation

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Impacts of different diameter combinations on the temperature of a crude oil pipeline when colocating

Bo YU, Yue SHI, Xin LIU, Jinjun ZHANG, Jinjia WEI,

《能源前沿（英文）》 2010年第4卷第2期页码 192-197 doi: 10.1007/s11708-009-0074-1

摘要： In order to show the effects of different diameter combinations on crude oil temperature when a crude oil pipeline and a products pipeline are laid in one trench, four typical diameter combinations are selected to conduct numerical simulation. After a series of calculations, the minimum mean temperature difference and the maximum temperature difference of the crude oil along the pipelines are obtained. In real pipeline constructions, the effects of other diameter combinations on crude oil temperature can be predicted by the method of linear interpolation to calculate results of the four diameter combinations obtained in this study.

关键词： technology of laying two pipelines in one trench diameter combinations crude oil temperature pipeline interval

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A review on catalytic & non-catalytic bio-oil upgrading in supercritical fluids

Sainab Omar, Yang Yang, Jiawei Wang

《化学科学与工程前沿（英文）》 2021年第15卷第1期页码 4-17 doi: 10.1007/s11705-020-1933-x

摘要： This review article summarizes the key published research on the topic of bio-oil upgrading using catalytic and non-catalytic supercritical fluid (SCF) conditions. The precious metal catalysts Pd, Ru and Pt on various supports are frequently chosen for catalytic bio-oil upgrading in SCFs. This is reportedly due to their favourable catalytic activity during the process including hydrotreating, hydrocracking, and esterification, which leads to improvements in liquid yield, heating value, and pH of the upgraded bio-oil. Due to the costs associated with precious metal catalysts, some researchers have opted for non-precious metal catalysts such as acidic HZSM-5 which can promote esterification in supercritical ethanol. On the other hand, SCFs have been effectively used to upgrade crude bio-oil without a catalyst. Supercritical methanol, ethanol, and water are most commonly used and demonstrate catalyst like activities such as facilitating esterification reactions and reducing solid yield by alcoholysis and hydrolysis, respectively.

关键词： bio-oil upgrading supercritical review

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Standard method design considerations for semi-quantification of total naphthenic acids in oil sands

Kevin A. Kovalchik, Matthew S. MacLennan, Kerry M. Peru, John V. Headley, David D.Y. Chen

《化学科学与工程前沿（英文）》 2017年第11卷第3期页码 497-507 doi: 10.1007/s11705-017-1652-0

摘要： Naphthenic acids are a complex class of thousands of naturally occurring aliphatic and alicyclic carboxylic acids found in oil sands bitumen and in the wastewater generated from bitumen processing. Dozens of analytical methods have been developed for the semi-quantification of total naphthenic acids in water samples. However, different methods can give different results, prompting investigation into the comparability of the many methods. A review of important methodological features for analyzing total naphthenic acids is presented and informs the design of future standard methods for the semi-quantification of total naphthenic acids using mass spectrometry. The design considerations presented are a synthesis of discussions from an Environment and Climate Change Canada (ECCC) led taskforce of 10 laboratory experts from government, industry and academia during April 2016 and subsequent discussions between University of British Columbia and ECCC representatives. Matters considered are: extraction method, solvent, pH, and temperature; analysis instrumentation and resolution; choice of calibration standards; use of surrogate and internal standards; and use of online or offline separation prior to analysis. The design considerations are amenable to both time-of-flight and Orbitrap mass spectrometers.

关键词： total naphthenic acids environmental samples oil sands process affected water polar organics mass spectrometry

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Exergy analysis of multi-stage crude distillation units

Xingang LI, Canwei LIN, Lei WANG, Hong LI

《化学科学与工程前沿（英文）》 2013年第7卷第4期页码 437-446 doi: 10.1007/s11705-013-1349-y

摘要： This paper aims to investigate the multi-stage effect on crude distillation units (CDUs) in thermodynamics. In this regard, we proposed three-, four-, five-, and six-stage CDU processes with all variables constrained to be almost the same except for the number of stages. We also analyzed the energy and exergy to assess the energy consumed by each process. Because additional distillation units would share the processing load and thus prevent products with low boiling points from overheating, the heat demand of the CDUs decreases with increasing stages and thus reduces the heat supply. Exergy loss is considered as a key parameter to assess these processes. When the exergy losses in heat exchangers are disregarded, the three- and four-stage CDUs have lower exergy losses than the five- and six-stage CDUs. When the overall exergy losses are considered, the optimum number of stages of CDUs depends on the exergy efficiency of heat integration.

关键词： exergy exergy loss crude oil distillation multi-stage energy saving

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油气管道流动保障技术发展趋势

李莉,苗青,佟文强,宋飞,徐海红,梁静华

《中国工程科学》 2010年第12卷第2期页码 47-51

摘要：

流动保障技术是通过综合研究影响油气管道流动安全各主要相关因素对所输介质流动特性的影响规律，进而提出保障和预防措施来实现油气管道的安全运行。对油气管道流动保障技术的历史、现状和未来趋势进行了论述，明确了所包含的原油流变学及其应用研究、油（气）管道流动改进剂研究与应用研究和多种油品顺序输送流动特性研究等三项主要研究内容，提出了这一研究领域的重点发展方向。

关键词：管道流动保障技术原油流变学管道流动改进剂顺序输送

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Strain localization analyses of idealized sands in biaxial tests by distinct element method

Mingjing JIANG, Hehua ZHU, Xiumei LI,

《结构与土木工程前沿（英文）》 2010年第4卷第2期页码 208-222 doi: 10.1007/s11709-010-0025-2

摘要： This paper presents a numerical investigation on the strain localization of an idealized sand in biaxial compression tests using the distinct element method (DEM). In addition to the dilatancy and material frictional angle, the principal stress field, and distributions of void ratio, particle velocity, and the averaged pure rotation rate (APR) in the DEM specimen are examined to illustrate the link between microscopic and macroscopic variables in the case of strain localization. The study shows that strain localization of the granular material in the tests proceeds with localizations of void ratio, strain and APR, and distortions of stress field and force chains. In addition, both thickness and inclination of the shear band change with the increasing of axial strain, with the former valued around 10–14 times of mean grain diameter and the later overall described by the Mohr-Coulomb theory.

关键词： idealized sand strain localization numerical analyses distinct element method (DEM)

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原油成品油管道同沟敷设新技术中的热力分析

凌霄,王艺,宇波,张劲军,达鑫,张争伟

《中国工程科学》 2008年第10卷第11期页码 30-36

摘要：

采用非结构化有限容积法，对原油成品油双管同沟敷设新技术进行数值模拟，详细研究了不同管间距下成品油管道对加热输送原油管道的热力影响，尤其是对热油油温的影响。

关键词：输油管道双管同沟敷设热力分析数值模拟管间距

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埋地热含蜡原油管道的非稳态传热问题

崔秀国,张劲军

《中国工程科学》 2003年第5卷第7期页码 77-83

摘要：

我国生产的原油大多为含蜡原油，加热输送是含蜡原油的主要输送方式。埋地热含蜡原油管道的运行中涉及若干复杂的非稳态传热问题。从管内原油传热（内部传热）和管道与外部环境的传热（外部传热）两方面，分析和总结了含蜡原油管道非稳态传热问题的研究现状，介绍了管道在土壤中传热的影响因素，比较了其各种解析和数值解法，阐述了管道停输状态下管内含蜡原油相变传热的规律及研究方法，讨论了非稳定流动状态下管内油流的水力—热力耦合问题及求解方法，指出了埋地热含蜡原油管道的非稳态传热方面需进一步研究的问题。

关键词：石蜡基原油管道输送非稳态传热

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Impact of crude distillation unit model accuracy on refinery production planning

Gang FU, Pedro A. Castillo CASTILLO, Vladimir MAHALEC

《工程管理前沿（英文）》 2018年第5卷第2期页码 195-201 doi: 10.15302/J-FEM-2017052

摘要： In this work, we examine the impact of crude distillation unit (CDU) model errors on the results of refinery-wide optimization for production planning or feedstock selection. We compare the swing cut+ bias CDU model with a recently developed hybrid CDU model (Fu et al., 2016). The hybrid CDU model computes material and energy balances, as well as product true boiling point (TBP) curves and bulk properties (e.g., sulfur % and cetane index, and other properties). Product TBP curves are predicted with an average error of 0.5% against rigorous simulation curves. Case studies of optimal operation computed using a planning model that is based on the swing cut+ bias CDU model and using a planning model that incorporates the hybrid CDU model are presented. Our results show that significant economic benefits can be obtained using accurate CDU models in refinery production planning.

关键词： impact of model accuracy on production planning swing cut+ bias CDU model hybrid CDU model refinery feedstock selection optimization optimization of refinery operation

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易凝高粘原油管输技术及其发展

张劲军

《中国工程科学》 2002年第4卷第6期页码 71-76

摘要：

我国所产原油80%以上为凝点较高的含蜡原油和粘稠的重质原油，其节能、安全输送一直是我国油气储运界面临的主要技术难题。简要介绍了这两类原油的流动特性及机理，概括了原油降凝减阻输送技术研究和应用的现状，分析了其发展趋势，提出了进一步研究需重点解决的问题。预计化学降凝剂改性仍将是含蜡原油节能安全输送技术的发展方向，目前需重点攻克大庆原油改性的难关；稠油乳化降粘减阻技术将得到更多的应用，在我国目前应重点针对海上油田的油水混输管道开展研究。现有技术的提升、新技术的涌现，有赖于基础研究的突破、技术路线的大胆创新和相关。

关键词：管道输送石蜡基原油重质原油降凝减阻化学添加剂

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Antioxidant and antitumor effects and immunomodulatory activities of crude and purified polyphenol extract

Xiaohong Kou,Lihua Han,Xingyuan Li,Zhaohui Xue,Fengjuan Zhou

《化学科学与工程前沿（英文）》 2016年第10卷第1期页码 108-119 doi: 10.1007/s11705-016-1553-7

摘要： The antioxidant and antitumor effects as well as the immunomodulatory activities of crude and purified polyphenol extract from blueberries were investigated. The antioxidant and antitumor effects of the polyphenol extract were measured both and , and their effect on the immune systems of CD-1 tumor-bearing mice were also analyzed. assays demonstrated that blueberry purified polyphenol extract (BBPP) exhibited higher antioxidant activities than blueberry crude polyphenol extract (BBCP), but the opposite effect was observed . Both the and antitumor activity and the immunity assay showed that BBCP not only inhibited tumor growth, but also significantly improved the immunity of the mice. According to physical and histological studies, the CD-1 tumor-bearing mice treated with the polyphenol extract, especially high doses of BBCP experienced a higher quality of life than the positive control group (treated with cyclophosphamide). These results indicate that BBCP has significant antioxidant and antitumor activities and that it can enhance the immunity of CD-1 tumor-bearing mice.

关键词： crude polyphenol extract purified polyphenol extract blueberry antioxidant antitumor immunity